作 者:蒋胜韬,等
影响因子:0.372
刊物名称:Fresenius Environmental Bulletin
出版年卷:2016, 25(5): 1467-1475
文章摘要:Driven by chemical substitution, Fe/Cu
bimetal materials were developed through copper
sedimentation on iron crumbs, and characterized
through a scanning electron microscope (SEM) and
X-ray electron spectrometers. Fe/Cu bimetal
systems were used in the treatment of
2,4-dinitrotoluene (2,4-DNT) chemical industrial
wastewater, whilst the research was made on
treatment efficiency and reaction rate based upon
respective factors ranging from the materials,
coverage rate of copper, pH and initial
concentration, etc. which led us into the discussion
of inner mechanisms. It was demonstrated that the
best coverage rate of copper plating is 0.25%, and
that Fe/Cu bimetal materials supersede simple iron
crumbs regarding removal efficiency, reaction rate
and adaptation. With pH set at 9.0, 11.0 and 13.0,
the removal of 2,4-dinitrotoluene increased by
6.22%, 9.52% and 25.26%, changing from iron
crumbs to Fe/Cu bimetal, reaching at 90.18%,
70.21% and 58.8% respectively. Fe/Cu bimetal
material tackles the low degradation efficiency in
alkaline environments faced by conventional
micro-electrolysis and is not limited within acidic
wastewater treatment.
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